Palladium-catalyzed stereoselective synthesis of (E,E)-1-arylselenobutadienes

DOI: 10.1055/s-1996-4362

Source and publish data:

Synthesis p. 1191 - 1192 (1996)

Update date:2022-08-03

Topics:

Authors:

Huang, Xian

Zhu, Liu-Sheng

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Article abstract of DOI:10.1055/s-1996-4362

(E)-Vinylic zirconium(IV) complexes, readily obtainable via hydrozirconation of alk-1-ynes, react with (E)-1-halo-2-arylselenoethylenes in the presence of catalytic amounts of tetrakis(triphenylphosphane)palladium to produce (E,E)-1-arylselenobutadienes in high yields.

Full text of DOI:10.1055/s-1996-4362

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Product name:(E,E)-4-phenyl-1-(4-methylphenylseleno)-1,3-butadiene

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