Tetrahedron p. 11529 - 11544 (1996)
Update date:2022-08-03
Topics:
Coperet, Christophe
Ma, Shengming
Sugihara, Takumichi
Negishi, Ei-Ichi
Termination of cyclic carbopalladation of alkynes via carbonylative lactamization can be achieved more satisfactorily with alkenyl or aryl halides containing an ω-carboxamido or ω-sulfonamido group than with those containing an ω-amino group. The method appears to be generally satisfactory for the preparation of fused cyclic systems consisting of six-membered rings, while the other cases require further development.
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