Synthesis and reactivity of tungsten(II) carbonyl η2-nitrile complexes: Crystal structure of tetrafluoroterephthalonitrile as a four-electron donor ligand

DOI: 10.1039/CC9960001691

Source and publish data:

Chemical Communications p. 1691 - 1692 (1996)

Update date:2022-08-03

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Authors:

Kiplinger, Jaqueline L.

Arif, Atta M.

Richmond, Thomas G.

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Article abstract of DOI:10.1039/CC9960001691

Treatment of a tungsten(II) carbonyl fluoride complex containing a tridentate monoanionic [C,N,N′] ligand with either pentafluorobenzonitrile or tetrafluoroterephthalonitrile affords tungsten(II) η²-nitrile complexes in which the nitrile ligand functions as a four-electron donor.

Full text of DOI:10.1039/CC9960001691

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