Tetrahedron Letters p. 5735 - 5738 (1996)
Update date:2022-09-26
Topics:
Islam, Md. Saiful
Kawano, Tomikazu
Hatanaka, Minoru
Ueda, Ikuo
3-Ethoxycarbonyl-2-propenylidene(triphenyl)phosphorane (2) reacted with glyoxal monohydrates (5) to give 2-substituted 5-ethoxycarbonylcyclopent-2-en-1-ones (6) by [3 + 2]-annulation reaction in the presence of a base. Compounds 6 were easily converted to 2-substituted cyclopent-2-en-1-ones by deethoxycarbonylation. An application of the annulation to synthesis of cis-jasmone is also described.
View MoreShijiazhuang Haitian Amino Acid Co., Ltd.
Contact:+86-311-88908111
Address:Shijiazhuang Hebei province,China
ClickChem Technology Co., Limited
Contact:+86-0310-6519966/0531-52893837
Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Taizhou KEDE Chemical.Co.,Ltd.
Contact:86-576-84613060
Address:Jiangkou Chemical Zoon
Hangzhou Donglou Bio-nutrient Co., Ltd.
Contact:+86-571-82225795,13967112289
Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.
Contact:+86-750-2881198
Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Doi:10.1021/jacs.9b09415
(2020)Doi:10.1016/S0022-328X(96)06532-1
(1996)Doi:10.1002/jhet.5570330619
(1996)Doi:10.1016/S0040-4039(96)02377-5
(1997)Doi:10.1016/s0020-1693(96)05185-7
(1997)Doi:10.1016/S0040-4020(96)01101-5
(1997)
