3-lithio-1-(triisopropylsilyl)indole, preparation and reactions with electrophilic reagents

DOI: 10.3987/com-96-7504

Source and publish data:

Heterocycles p. 1713 - 1718 (1996)

Update date:2022-08-03

Topics:

Authors:

Amat, Mercedes

Sathyanarayana, Swargam

Hadida, Sabine

Bosch, Joan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.3987/com-96-7504

3-Lithio-1-(triisopropylsilyl)indole (2) is prepared by halogenmetal exchange from the corresponding 3-bromoindole and regioselectively reacts with a variety of electrophilic reagents to give 3-substituted indoles.

Full text of DOI:10.3987/com-96-7504

Products guided by the article

Product name:Phenyl-(1-triisopropylsilanyl-1H-indol-3-yl)-methanone

Cas No:181780-84-7

R&D Labs maybe for 181780-84-7

Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
Suzhou BEC Fine Chemicals Co., Ltd.

website:http://www.bek.com.cn

Contact:0512-68095917　 18913193865

Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside
Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China

Relevant to this article

Chloromethylation on phenol derivatives

Doi:10.1248/yakushi1947.88.1_116
(1968)
Uncatalysed (thermal) and Lewis acid-promoted asymmetric hetero-Diels-Alder reaction of 1-thiabuta-1,3-dienes (thiochalcones) with di-(-)-menthyl fumarate. Configuration determination by X-ray crystallographic analysis of (2S,3R,4R)-(+)-2,3-bis[(-)-menthoxycarbonyl]-4,6-diphenyl-3,4-dihydro-2H- thiopyran and conversion of cycloadducts into optically pure diols

Doi:10.1039/P19960001897
(1996)
Nickel(II) thiolate complex with carbon monoxide and its Fe(II) analog: Synthetic models for CO adducts of nickel-iron-containing enzymes

Doi:10.1021/ja961968r
(1996)
New phosphabenzenes by [4 + 2] cycloaddition of stannoles to 1-phospha-1-alkynes - Determination of signs of coupling constants [ⁿJ(³¹P, ¹³C), ⁿJ(³¹P, ¹H), ²J(³¹P, ²⁹Si), ²J(¹¹⁹Sn, ³¹P)]

Doi:10.1016/0022-328X(96)06316-4
(1996)
The chemistry of 1,3,5-triazacyclohexane complexes 5: Cationic zinc(II) alkyl complexes of N-alkylated 1,3,5-triazacyclohexanes and 13-benzyl-l,5,9-triazatricyclo[7.3.1.0^5,13]-tridecane

Doi:10.1016/0022-328X(96)06271-7
(1996)
5-alkyl-l-pyrazinecarboxamides, 5-alkyl-2-pyrazinecarbonitriles and 5-alkyl-2-acetylpyrazines as synthetic intermediates for antiinflammatory agents

Doi:10.1135/cccc19961093
(1996)

Article Doi