The asymmetric synthesis of allylglycine and other unnatural α-amino acid via zinc-mediated allylation of oximes in aqueous media

DOI: 10.1016/0040-4039(96)01118-5

Source and publish data:

Tetrahedron Letters p. 5273 - 5276 (1996)

Update date:2022-08-04

Topics:

Authors:

Hanessian, Stephen

Yang, Rui-Yang

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Article abstract of DOI:10.1016/0040-4039(96)01118-5

Enantiomerically pure or highly enriched allylglycine and its chain-substituted analogs are easily accessible from the reaction of the sultam derivative of O-benzyl glyoxylic acid oxime with allylic bromides in the presence of powdered zinc in aqueous ammonium chloride.

Full text of DOI:10.1016/0040-4039(96)01118-5

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