Stereoselective nucleophilic epoxidation of hydroxy vinyl sulfoxide derivatives

DOI: 10.1016/S0040-4039(96)01481-5

Source and publish data:

Tetrahedron Letters p. 6793 - 6796 (1996)

Update date:2022-08-04

Topics:

Authors:

Fernandez De La Pradilla, Roberto

Manzano, Pilar

Priego, Julian

Viso, Alma

Martinez-Ripoll, Martin

Rodriguez, Ana

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Article abstract of DOI:10.1016/S0040-4039(96)01481-5

The diastereoslectivity of the nucleophilic epoxidation of vinyl sulfoxides bearing oxygenated substituents at allylic positions, 1-4, with MOO-t-Bu (M = Na, K) is primarily controlled by the chiral sulfur atom.

Full text of DOI:10.1016/S0040-4039(96)01481-5

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