Stereoselective nucleophilic epoxidation of hydroxy vinyl sulfoxide derivatives

DOI: 10.1016/S0040-4039(96)01481-5

Source and publish data:

Tetrahedron Letters p. 6793 - 6796 (1996)

Update date:2022-08-04

Topics:

Authors:

Fernandez De La Pradilla, Roberto

Manzano, Pilar

Priego, Julian

Viso, Alma

Martinez-Ripoll, Martin

Rodriguez, Ana

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(96)01481-5

The diastereoslectivity of the nucleophilic epoxidation of vinyl sulfoxides bearing oxygenated substituents at allylic positions, 1-4, with MOO-t-Bu (M = Na, K) is primarily controlled by the chiral sulfur atom.

Full text of DOI:10.1016/S0040-4039(96)01481-5

Products guided by the article

Product name:(+)-(1'R,2R,3R,S_S)-3-n-butyl-2-(1'-hydroxypropyl)-2-(p-tolylsulfinyl)oxirane

Cas No:182879-13-6

R&D Labs maybe for 182879-13-6

Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Wuhan Silworld Chemical Co.,Ltd

website:http://www.silworldchemical.com

Contact:+86-27-85613400

Address:No.198 jiangjun Road, Wuhan,China 430033
Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province

Relevant to this article

Doi:10.1021/ja01617a047
(1955)
Exceptional electronic modulation of porphyrins through meso-arylethynyl groups. Electronic spectroscopy, electronic structure, and electrochemistry of [5,15-bis](aryl)ethynyl]-10,20-diphenylporphinato]zinc(II) complexes

Doi:10.1021/ja962403y
(1996)
1,4,7-trithiacyclononane ([9]aneS₃) and 2,5,8-trithia[9]orthocyclophane complexes of molybdenum(II) and tungsten(II): Crystal structures of [WI(CO)₃([9]aneS₃)][BPh₄] and [WI₂(CO)₃(NCMe)(PPh₃)]

Doi:10.1039/dt9960004003
(1996)
Preparation and Protonation Studies of trans-Dioxorhenium(V) Complexes with Imidazoles

Doi:10.1021/ic960451d
(1996)
pH-sensitive exciton chirality chromophore. Solvatochromic effects on circular dichroism spectra

Doi:10.1016/0957-4166(96)00372-2
(1996)
"breathing" vesicles with jellyfish-like on-off switchable fluorescence behavior

Doi:10.1002/anie.201206362
()

Article Doi