Stereoselective nucleophilic epoxidation of hydroxy vinyl sulfoxide derivatives

DOI: 10.1016/S0040-4039(96)01481-5

Source and publish data:

Tetrahedron Letters p. 6793 - 6796 (1996)

Update date:2022-08-04

Topics:

Authors:

Fernandez De La Pradilla, Roberto

Manzano, Pilar

Priego, Julian

Viso, Alma

Martinez-Ripoll, Martin

Rodriguez, Ana

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(96)01481-5

The diastereoslectivity of the nucleophilic epoxidation of vinyl sulfoxides bearing oxygenated substituents at allylic positions, 1-4, with MOO-t-Bu (M = Na, K) is primarily controlled by the chiral sulfur atom.

Full text of DOI:10.1016/S0040-4039(96)01481-5

Products guided by the article

Product name:(+)-(1'R,2R,3R,S_S)-3-n-butyl-2-(1'-hydroxypropyl)-2-(p-tolylsulfinyl)oxirane

Cas No:182879-13-6

R&D Labs maybe for 182879-13-6

Hangzhou Sartort Biopharma Co., Ltd

website:http://www.sartort.com

Contact:86-571-87039693

Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Golden Union Agrochemical Import and Export Co., Ltd.

Contact:86-755-23910527

Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Nanjing Qirui Material Co., Ltd.

Contact:+86-25-52320053

Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China

Relevant to this article

Doi:10.1021/ja01617a047
(1955)
Exceptional electronic modulation of porphyrins through meso-arylethynyl groups. Electronic spectroscopy, electronic structure, and electrochemistry of [5,15-bis](aryl)ethynyl]-10,20-diphenylporphinato]zinc(II) complexes

Doi:10.1021/ja962403y
(1996)
1,4,7-trithiacyclononane ([9]aneS₃) and 2,5,8-trithia[9]orthocyclophane complexes of molybdenum(II) and tungsten(II): Crystal structures of [WI(CO)₃([9]aneS₃)][BPh₄] and [WI₂(CO)₃(NCMe)(PPh₃)]

Doi:10.1039/dt9960004003
(1996)
Preparation and Protonation Studies of trans-Dioxorhenium(V) Complexes with Imidazoles

Doi:10.1021/ic960451d
(1996)
pH-sensitive exciton chirality chromophore. Solvatochromic effects on circular dichroism spectra

Doi:10.1016/0957-4166(96)00372-2
(1996)
"breathing" vesicles with jellyfish-like on-off switchable fluorescence behavior

Doi:10.1002/anie.201206362
()

Article Doi