A Horner-Wittig synthesis of 1-chlorovinyl sulfoxides

Article abstract of DOI:10.1080/10426509608545187

1-Chlorovinyl sulfoxides 1 were prepared by Horner-Wittig reaction of the readily accessible [(α-chloro)sulfinylmethyl)diphenylphosphine oxides 2 with aldehydes. Excellent Z-selectivity was observed in most cases.

Full text of DOI:10.1080/10426509608545187

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Phosphorus, Sulfur, and Silicon and
the Related Elements
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A Horner-Wittig Synthesis of 1-
Chlorovinyl Sulfoxides.
P.A. Otten , H.M. Davies & A. Van Der Gen
a Leiden Institute of Chemistry, Gorlaeus Laboratories ,
P.O. Box 9502, 2300 RA Leiden, The Netherlands
b Leiden Institute of Chemistry, Gorlaeus Laboratories ,
P.O. Box 9502, 2300 RA Leiden, The Netherlands
c Leiden Institute of Chemistry, Gorlaeus Laboratories ,
P.O. Box 9502, 2300 RA Leiden, The Netherlands
Published online: 06 Aug 2008.
To cite this article: P.A. Otten , H.M. Davies & A. Van Der Gen (1996) A Horner-Wittig
Synthesis of 1-Chlorovinyl Sulfoxides., Phosphorus, Sulfur, and Silicon and the Related
Elements, 109:1-4, 449-452, DOI: 10.1080/10426509608545187
To link to this article: http://dx.doi.org/10.1080/10426509608545187
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