Synthesis, photophysics and electrochemistry of [Au2(dppf)R2] [dppf = Fe(η-C5H4PPh2)2; R = alkyl, aryl or alkynyl]. Crystal structure of [Au2(dppf)(C16H9)2] (C16H9 = pyren-1-yl)

DOI: 10.1039/DT9960003411

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3411 - 3415 (1996)

Update date:2022-07-30

Topics:

Authors:

Yam, Vivian Wing-Wah

Choi, Sam Wing-Kin

Cheung, Kung-Kai

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Article abstract of DOI:10.1039/DT9960003411

A series of organometallic complexes [Au₂(dppf)R₂] [dppf = Fe(η-C₅H₄PPh₂)₂; R = Me, Ph, 1-naphthyl, 9-anthryl, pyren-1-yl (C₁₆H₉), C≡CPh or C≡CBu^t] have been synthesized. Their photophysical and electrochemical properties have been studied. Both excimer and exciplex formation are evidenced in [Au(dppf)₂(C₁₆H₉)₂]. The crystal structure of the latter has been determined.

Full text of DOI:10.1039/DT9960003411

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