Tetrahedron Asymmetry p. 2743 - 2754 (1996)
Update date:2022-08-02
Topics: Lipase Acylation Enantioselective Enantioselective synthesis Prochiral
Yokomatsu, Tsutomu
Sato, Mutsumi
Shibuya, Shiroshi
Lipase PS catalyzed acetylation of prochiral 2-(ω-phosphono)alkyl-1,3-propanediols 1a-c was found to proceed with high enantioselectivity. The applications of phosphonic chirons 2a-c thus obtained were illustrated by the stereocontrolled synthesis of ω-phosphono-α-amino acids such as L-AP-3, L-AP-4, and N-Boc-L-F2Pab(OEt)2-OH.
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Doi:10.1002/anie.199622261
(1996)Doi:10.1021/ja970251g
(1997)Doi:10.1021/acs.orglett.0c02995
(2020)Doi:10.1016/0957-4166(96)00348-5
(1996)Doi:10.1039/a903370j
(1999)Doi:10.1016/S0040-4039(00)71487-0
(1980)
