Angewandte Chemie - International Edition in English p. 2226 - 2228 (1996)
Update date:2022-08-02
Topics:
Bochmann
Dawson
On the last hitherto unknown simple metallocenes, the aluminocenium cation [Al(η-C5H5)2]+ 1, is readily accessible from [AlCp2Me] and B(C6F5)3. The spectroscopic data are consistent with a metallocene structure. The complex is a highly efficient initiator for the carbocationic polymerization of isobutene and the industrially important copolymerization of isobutene and isoprene.
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Doi:10.1016/S0040-4039(00)71487-0
(1980)Doi:10.1039/CC9960002271
(1996)Doi:10.1021/ja501979g
(2014)Doi:10.1016/0040-4039(96)01779-0
(1996)Doi:10.1080/00945719608005138
(1996)Doi:10.1139/v67-467
(1967)
