Tetrahedron Letters p. 7465 - 7468 (1996)
Update date:2022-07-29
Topics:
Cavalla, David
Gueguen, Catherine
Nelson, Adam
O'Brien, Peter
Russell, Matthew G.
Warren, Stuart
Single diastereomers of β-keto phosphine oxides have been generated from intermolecular acylation of phosphine oxides using either chiral esters or chiral phosphine oxides. In some cases, reduction of the ketone products was not affected by the presence of extra chiral centres. Some mechanistic points of interest in the acylation reactions are discussed.
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