Electronic Structure of Axially Distorted Molybdenum(V) Complexes; an Absorption Spectral Study

DOI: 10.1039/DT9900002999

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Journal of the Chemical Society, Dalton Transactions p. 2999 - 3006 (1990)

Update date:2022-08-02

Topics:: Authors:

Collison, David

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Article abstract of DOI:10.1039/DT9900002999

Electronic absorption spectra of a range of molybdenum(V) compplexes and ^- have been measured in the temperature range 4.2-300 K and in the energy range 4 000-40 000 cm^-1.The absorption bands below 18 000 cm^-1 have been assigned to the one-electron promotion d_xy^* <*> d_xz^*, d_yz^*.Bands in the visible region have been classified as type I (d_xy^* <*> d_x2_-y2^*) or type II (in-plane ligand-to-metal charge transfer).Assignments of the absorption spectra of the chromophores MoO³⁺, VO²⁺, WO³⁺, MoN²⁺, RuN³⁺, and OsN³⁺ have been compared to produce a self-consistent assignment.

Full text of DOI:10.1039/DT9900002999

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Electronic Structure of Axially Distorted Molybdenum(V) Complexes; an Absorption Spectral Study

DOI: 10.1039/DT9900002999

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Article abstract of DOI:10.1039/DT9900002999

Full text of DOI:10.1039/DT9900002999

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