Journal of the Chemical Society, Dalton Transactions p. 4129 - 4134 (1996)
Update date:2022-08-03
Topics:
Beer, Paul D.
Drew, Michael G. B.
Graydon, Andrew R.
New acyclic mono-, bis- and tris-cobaltocenium receptors containing aryl, biaryl and pyridine amide moieties have been synthesized and shown from 1H NMR anion-binding studies to exhibit chloride and dihydrogenphosphate anion-selectivity preferences dependent upon the nature of the amide substituent. The single-crystal structure of a chloride complex of one of the receptors has been determined and electrochemical investigations showed that the chloride-selective cobaltocenium derivatives electrochemically sense the halide anion in acetonitrile solution.
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