ADDITION OF AN ELECTROPHILIC CARBENE TO AN ELECTRON-DEFICIENT OLEFIN. KINETICS OF BENZYLCHLOROCARBENE-DIETHYL FUMARATE REACTION

DOI: 10.1016/S0040-4039(00)98621-0

Source and publish data:

Tetrahedron Letters p. 3071 - 3074 (1985)

Update date:2022-08-03

Topics:

Authors:

Liu, Michael T. H.

Subramanian, R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)98621-0

Benzylchlorocarbene reacts as an electrophile with electronic deficient diethyl fumerate; the dependence of product ratio is consistent with formation of a carbene adduct.

Full text of DOI:10.1016/S0040-4039(00)98621-0

Products guided by the article

Product name:Z-β-chlorostyrene

Cas No:18684-86-1

R&D Labs maybe for 18684-86-1

Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Hefei EnliPharma Tecnology Co.,Ltd

Contact:0086-551-66399836

Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist

Relevant to this article

Synthesis of (15E)-3β-hydroxyandrost-5-ene-15,17-dione 15-(O-carboxymethyl)oxime; The new hapten for 3β-hydroxyandrost-5-en-17-one(dehydroepiandrosterone, dhea)

Doi:10.1135/cccc19961647
(1996)
3-Amino-1,2,4-oxadiazol-5-ones as prodrugs for hydroxyguanidines

Doi:10.1002/ardp.19963291205
(1996)
Enantioselective Synthesis of Aurilide, a Cytotoxic 26-Membered Cyclodepsipeptide of Marine Origin

Doi:10.1055/s-1997-753
(1997)
Synthesis and Cytotoxic Evaluation of Pyrrole Hetarylazoles Containing Benzimidazole/Pyrazolone/1,3,4-Oxadiazole Motifs

Doi:10.1002/jhet.2501
(2016)
Doi:10.1038/modpathol.3880230
()
Reactions of silyl-substituted Fischer-type carbene complexes with silanes

Doi:10.1016/S0022-328X(00)00721-X
(2001)

Article Doi