ADDITION OF AN ELECTROPHILIC CARBENE TO AN ELECTRON-DEFICIENT OLEFIN. KINETICS OF BENZYLCHLOROCARBENE-DIETHYL FUMARATE REACTION

DOI: 10.1016/S0040-4039(00)98621-0

Source and publish data:

Tetrahedron Letters p. 3071 - 3074 (1985)

Update date:2022-08-03

Topics:

Authors:

Liu, Michael T. H.

Subramanian, R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)98621-0

Benzylchlorocarbene reacts as an electrophile with electronic deficient diethyl fumerate; the dependence of product ratio is consistent with formation of a carbene adduct.

Full text of DOI:10.1016/S0040-4039(00)98621-0

Products guided by the article

Product name:Z-β-chlorostyrene

Cas No:18684-86-1

R&D Labs maybe for 18684-86-1

Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Jiangsu Feymer Technology Co., Ltd.

Contact:+86-512-58110132

Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct

Relevant to this article

Synthesis of (15E)-3β-hydroxyandrost-5-ene-15,17-dione 15-(O-carboxymethyl)oxime; The new hapten for 3β-hydroxyandrost-5-en-17-one(dehydroepiandrosterone, dhea)

Doi:10.1135/cccc19961647
(1996)
3-Amino-1,2,4-oxadiazol-5-ones as prodrugs for hydroxyguanidines

Doi:10.1002/ardp.19963291205
(1996)
Enantioselective Synthesis of Aurilide, a Cytotoxic 26-Membered Cyclodepsipeptide of Marine Origin

Doi:10.1055/s-1997-753
(1997)
Synthesis and Cytotoxic Evaluation of Pyrrole Hetarylazoles Containing Benzimidazole/Pyrazolone/1,3,4-Oxadiazole Motifs

Doi:10.1002/jhet.2501
(2016)
Doi:10.1038/modpathol.3880230
()
Reactions of silyl-substituted Fischer-type carbene complexes with silanes

Doi:10.1016/S0022-328X(00)00721-X
(2001)

Article Doi