Tetrahedron Letters p. 8643 - 8646 (1996)
Update date:2022-08-05
Topics:
Stamos, Dean P.
Kishi, Yoshito
A practical, scalable synthesis of the C.1-C.13 segment of halichondrin B has been developed starting from L-mannonic-γ-lactone, using C-allylation/oxy-Michael cyclization and Ni(II)/Cr(II)-mediated vinyltrimethylsilane addition to set the C.6/C.3 and C.11 stereocenters, respectively.
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Doi:10.1006/jcht.1993.1009
(1993)Doi:10.1016/j.steroids.2017.01.005
(2017)Doi:10.1002/(SICI)1099-1344(199612)38:12<1071::AID-JLCR924>3.0.CO;2-V
(1996)Doi:10.1016/S0020-1693(96)05117-1
(1997)Doi:10.1039/P19960002851
(1996)Doi:10.1021/jo962099r
(1997)
