Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 1677 - 1690 (1996)
Update date:2022-08-03
Topics:
Ramesh
Natarajan
Several new hexa-coordinated ruthenium(III) complexes of the type [RuX2(EPh3)2(LL')], (X = Cl or Br; E = P or As) [where LL' = morpholinedithiocarbamate (Morphdtc), piperidinedithiocarbamate (Pipdtcl and piperazinedithiocarbamate (Pzdtc) have been synthesised. In all these complexes the heterocyclic dithiocarbamates behave as a uninegative bidentate (SS) chelating ligand. It has been observed that the incoming ligand replaces a halide, a tertiary phosphine/arsine and methanol from the starting complexes. All the complexes have been characterised on the basis of analytical and spectroscopic data. The new complexes showed a reasonable amount of antifungal activities.
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