Tetrahedron p. 15147 - 15156 (1996)
Update date:2022-08-03
Topics:
Gros, Philippe
Hansen, Philippe
Caubere, Paul
Bis(phenylthio)methane and [1,3]-dithiane were efficiently deprotonated by the NaNH2-Et(OCH2CH2)2-ONa complex base. A marked behaviour difference was observed between the sodium carbanion of [1,3]-dithiane and the corresponding lithio-derivative. A 'radicaloid' mechanism is proposed to explain the results observed.
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