Journal of the Chemical Society. Perkin transactions I p. 2803 - 2809 (1996)
Update date:2022-08-05
Topics:
Bonini, Bianca Flavia
Comes-Franchini, Mauro
Fochi, Mariafrancesca
Mazzanti, Germana
Peri, Francesca
Ricci, Alfredo
Aliphatic silyl thioketones containing an α-hydrogen atom undergo enethiolization to Z-α-silyl enethiols 2. Compounds 2 react with a variety of halides R3X to give open-chain α-silyl vinyl sulfides 3. Protiodesilylation of 3 was achieved upon treatment with fluoride ion to give vinyl sulfides 4. Reaction of 3 with Grignard reagents, in the presence of an appropriate nickel catalyst, results in a series of vinylsilanes 5 with a specific geometry.
View MoreContact:+1 (647) 918 5848
Address:2343 BRIMLEY RD., Suite 250
Chongqing Changfeng Chemical Co., Ltd.
website:http://www.changfengchem.com
Contact:+86-23-67896333
Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
zhangjiagang bonded areas banggao co;ltd
website:http://www.shunchangchem.com
Contact:0086-13921972933
Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province
Chongqing Shuangfeng Chemical Co.,Ltd
Contact:+86-23-49850156
Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Chengdu Sino-Strong Pharmaceutical Co.,Ltd.
website:http://www.sino-strong.com.cn
Contact:+86-28-82666753
Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China
Doi:10.1016/S0022-328X(96)06569-2
(1996)Doi:10.1021/ja962631s
(1997)Doi:10.1016/S0022-328X(96)06475-3
(1996)Doi:10.1002/chem.200400358
(2004)Doi:10.1021/ja01099a047
(1953)Doi:10.1016/S0040-4020(01)99384-6
(1973)
