Journal of the Chemical Society. Perkin transactions I p. 2803 - 2809 (1996)
Update date:2022-08-05
Topics:
Bonini, Bianca Flavia
Comes-Franchini, Mauro
Fochi, Mariafrancesca
Mazzanti, Germana
Peri, Francesca
Ricci, Alfredo
Aliphatic silyl thioketones containing an α-hydrogen atom undergo enethiolization to Z-α-silyl enethiols 2. Compounds 2 react with a variety of halides R3X to give open-chain α-silyl vinyl sulfides 3. Protiodesilylation of 3 was achieved upon treatment with fluoride ion to give vinyl sulfides 4. Reaction of 3 with Grignard reagents, in the presence of an appropriate nickel catalyst, results in a series of vinylsilanes 5 with a specific geometry.
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