Journal of the Chemical Society, Dalton Transactions p. 4471 - 4478 (1996)
Update date:2022-08-03
Topics:
Dann, Sandra E.
Genge, Anthony R. J.
Levason, William
Reid, Gillian
The compounds SnX4 reacted with 1 molar equivalent of dithioether, L-L, in dry CHCl3 solution to give the six-co-ordinate species [SnX4(L-L)] [X = Cl, L-L = MeS(CH2)nSMe, o-C6H4(SMe)2 or PhS(CH2)nSPh (n = 2 or 3); X = Br, L-L = MeS(CH2)nSMe or o-C6H4(SMe)2] in high yield as white or pale yellow powdered solids. Using SnBr4 and PhS(CH2)nSPh or SnI4 with MeS(CH2)nSMe did not produce isolable products, although solution 119Sn-{1H} NMR spectroscopy provided evidence for their existence at low temperatures. X-Ray structural studies on [SnCl4{MeS(CH2)2SMe}], [SnCl4{MeS(CH2)3SMe}], [SnCl4{o-C6H4(SMe)2}], [SnCl4{PhS(CH2)3SPh}] and [SnBr4{MeS(CH2)3SMe}] confirmed an S2X4 donor set with the dithioether acting as a bidentate chelate. Variable-temperature solution 1H and 119Sn-{1H} NMR spectroscopic studies showed that the complexes are extremely labile and ligand dissociation and pyramidal inversion are fast except at low temperatures. Magic angle spinning 119Sn NMR data for [SnCl4(L-L)] are reported. The crystal structure of cis-[SnI4{MeS(O)(CH2)3SMe}2], obtained as a decomposition product from the SnI4-MeS(CH2)3SMe reaction, shows monodentate sulfoxide (O) co-ordination.
Contact:1-858-6993322
Address:9883 Pacific Heights Blvd., Suite H, San Diego
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)
Contact:010-52876516
Address:tongzhoubeiyuan
Contact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Rudong Zhenfeng Yiyang Chemical Co., Ltd.
Contact:0513-84573047
Address:South Fengli Town, Rudong County, Jiangsu Province, China
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Doi:10.1021/jo01254a029
(1969)Doi:10.1039/c9cy02498k
(2020)Doi:10.1016/0022-328X(90)85408-Q
(1990)Doi:10.1007/s10600-007-0063-8
(2007)Doi:10.1081/NCN-100002349
(2001)Doi:10.1007/BF00798443
(1983)
