1-Amido-3-(1H)-1,2-benziodoxoles: Stable amidoiodanes and reagents for direct amidation of organic substrates

Article abstract of DOI:10.1016/S0040-4039(96)02245-9

Amidobenziodoxoles 2 can be prepared from benziodoxole 1, trimethylsilyltriflate and the appropriate amides in the form of stable, microcrystalline compounds. Amidobenziodoxoles 2 react with adamantane 3 or N,N-dimethylarylamines 5 to afford the corresponding products of amidation, 4 and 6.