Stereocontrolled synthesis of C10-C22 fragment of the immunosuppressant FK 506. An occurrence of complementary stereoselectivity in the C15 ketone reduction

DOI: 10.1016/S0957-4166(96)00445-4

Source and publish data:

Tetrahedron Asymmetry p. 3371 - 3390 (1996)

Update date:2022-07-30

Topics:

Authors:

Morimoto, Yoshiki

Mikami, Atsushi

Kuwabe, Shin-Itsu

Shirahama, Haruhisa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(96)00445-4

The stereoselective syntheses of the C10-C22 fragment 2a and its C15-epimer 2b of the immunosuppressant FK 506 1 have been carried out through convergent coupling of the sulfone 3, which could be constructed by highly stereocontrolled ester-enolate Claise

Full text of DOI:10.1016/S0957-4166(96)00445-4

Products guided by the article

Product name:(2S,4S,5S)-4-formyl-2-phenyl-5-(2-propenyl)-1,3-dioxacyclohexane

Cas No:186406-53-1

R&D Labs maybe for 186406-53-1

Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China

Relevant to this article

Doi:10.1016/0040-4020(79)85049-8
(1979)
Phenacenes: A family of graphite ribbons. 2. Syntheses of some [7]phenacenes and an [11]phenacene by stilbene-like photocyclizations

Doi:10.1021/ja9638418
(1997)
Preparation and characterization of [Re(bpy)( CO)₃L][SbF₆] (L = phosphine, phosphite)

Doi:10.1016/S0022-328X(96)06658-2
(1997)
1-Azaspiro[4.4]nonane-2,6-dione and the separation and absolute configurations of its enantiomers

Doi:10.1016/S0957-4166(96)00509-5
(1997)
Corrigendum to: Dimethyl Sulfoxide Participating in Copper(I) Iodide-Catalyzed Cascade Oxidation/Formylation Reactions: The Synthesis of α-Formylpyrroles from 2,3-Dihydro-1 H -pyrroles (Advanced Synthesis & Catalysis, (2014), 356, 14-15, (3119-3124), 10.1

Doi:10.1002/adsc.201401104
(2014)
Aurilide, a cytotoxic depsipeptide from the sea hare Dolabella auricularia: Isolation, structure determination, synthesis, and biological activity

Doi:10.1016/j.tet.2004.06.125
(2004)

Article Doi