Energetics of hydrate and hemiketal formation for highly fluorinated ketones

DOI: 10.1016/S0040-4039(96)02149-1

Source and publish data:

Tetrahedron Letters p. 9165 - 9168 (1996)

Update date:2022-09-26

Topics:

Authors:

Lindner, Patrick E.

Lemal, David M.

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Article abstract of DOI:10.1016/S0040-4039(96)02149-1

Heats of hydration for a series of fluoroketones have been calculated at the HF/6-31G**//6-31G** level, and equilibrium constants for hemiketal formation with trifluoroethanol have been measured for a related series. These reactions were found to be consi

Full text of DOI:10.1016/S0040-4039(96)02149-1

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