Enantiomeric haloruthenocenium salts: Synthesis of the first representatives with the use of asymmetric reduction and asymmetric cyclopalladation

DOI: 10.1016/S0022-328X(96)06335-8

Source and publish data:

Journal of Organometallic Chemistry p. 181 - 186 (1996)

Update date:2022-08-02

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Authors:

Mamedyarova, Irina A.

Nefedova, Marina N.

Sokolov, Viatcheslav I.

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Article abstract of DOI:10.1016/S0022-328X(96)06335-8

Optically active substituted ruthenocenes, (+)-RcCH(OH)Ph (I), (-)-RcCH(Me)Ph (II) and (+)-1-hydroxymethyl-2-methylruthenocene (VIII) react with molecular iodine to yield the corresponding iodoruthenocenium salts Ia, IIa, VIIIa with I^-_{3
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Full text of DOI:10.1016/S0022-328X(96)06335-8

Products guided by the article

Product name:(C₅H₅)RuI(C₅H₄CH(OH)C₆H₅)⁽¹⁺⁾*I₃^(1-)=[(C₅H₅)RuI(C₅H₄CH(OH)C₆H₅)]I₃

Cas No:186822-84-4

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