Welcome to LookChem.com Sign In|Join Free

Article Doi

Novel Binuclear Vanadium(V)-Schiff Base Cations containing Single Fluorine Bridges and the Structure of Difluorodioxovanadate(1-)

DOI: 10.1039/DT9940002591

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2591 - 2598 (1994)

Update date:2022-08-03

Topics:

Authors:

Fairhurst, Shirley A.Fairhurst, Shirley A.

Hughes, David L.Hughes, David L.

Leigh, G. JefferyLeigh, G. Jeffery

Sanders, J. RogerSanders, J. Roger

Weisner, JanWeisner, Jan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940002591

The complex reacted with HBF4*Et2O in air to produce the novel linear species <2(μ-F)>(+), the structure of which has been determined as its BF4(-) and (-) salts.The perchlorate and triflate (O3SCF3(-)) salts have been characterised spectroscopically and analytically, as well as the tetrafluoroborate homologues from salicylaldehyde and 2-methylpropylenediamine, and from ethylenediamine and 3-methoxysalicylaldehyde.The (-) is mononuclear in the above salt, as well as in , compared to a polynuclear form found in .The mononuclear anion was also fully characterised by 19F and 51V NMR spectroscopy.

View More

Products guided by the article

Product name:F2O2V(1-)

Cas No:18785-24-5

18785-24-5

R&D Labs maybe for 18785-24-5

Relevant to this article

Hot Product