Novel Binuclear Vanadium(V)-Schiff Base Cations containing Single Fluorine Bridges and the Structure of Difluorodioxovanadate(1-)

DOI: 10.1039/DT9940002591

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2591 - 2598 (1994)

Update date:2022-08-03

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Authors:

Fairhurst, Shirley A.

Hughes, David L.

Leigh, G. Jeffery

Sanders, J. Roger

Weisner, Jan

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Article abstract of DOI:10.1039/DT9940002591

The complex reacted with HBF4*Et2O in air to produce the novel linear species <2(μ-F)>(+), the structure of which has been determined as its BF4(-) and (-) salts.The perchlorate and triflate (O3SCF3(-)) salts have been characterised spectroscopically and analytically, as well as the tetrafluoroborate homologues from salicylaldehyde and 2-methylpropylenediamine, and from ethylenediamine and 3-methoxysalicylaldehyde.The (-) is mononuclear in the above salt, as well as in , compared to a polynuclear form found in .The mononuclear anion was also fully characterised by 19F and 51V NMR spectroscopy.

Full text of DOI:10.1039/DT9940002591

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