Tetrahedron p. 9179 - 9186 (1996)
Update date:2022-08-03
Topics:
Bartoli, Giuseppe
Bosco, Marcella
Dalpozzo, Renato
De Nino, Antonio
Iantorno, Emma
Tagarelli, Antonio
Palmieri, Gianni
α'- and γ-Dianions of β-(monoalkylamino) α,β-unsaturated ketones react with trialkylchlorosilanes leading to α'- and γ-trialkylsilylenaminones. Conversely from trimethylchlorosilane, the reaction between dianions of 3-(N-isopropylamino)-1-arylbut-2-en-1-ones and t-butyldimethylchlorosilane or triisopropylchlorosilane leads to the corresponding 4-trialkylsilyl derivatives. An explanation of these findings is reported. Hydrolysis of these compounds affords the until now unknown α' silylated β-diketones.
View MoreSuzhou HeChuang Chemical Co.,Ltd.
Contact:+86-512-88800520
Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Contact:86-512-69362780,69362785
Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Contact:+86-512-56795332
Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Zhengzhou Xinlian Chemical Tech Co. ,Ltd
Contact:0371-65771781 021-52042910
Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Doi:10.1021/jo01256a023
(1969)Doi:10.1016/S0040-4020(97)00139-7
(1997)Doi:10.1016/S0040-4020(97)00125-7
(1997)Doi:10.1021/jo970743b
(1997)Doi:10.1016/S0040-4020(97)00098-7
(1997)Doi:10.1002/jhet.5570160727
(1979)