Synthesis of 2-azabicyclo[3.3.1]lnonanes by means of (carbamoyl)dichloromethyl radical cyclization

DOI: 10.1016/S0040-4020(96)01051-4

Source and publish data:

Tetrahedron p. 1391 - 1402 (1997)

Update date:2022-08-03

Topics:

Authors:

Quirante, Josefina

Escolano, Carmen

Massot, Mireia

Bonjoch, Josep

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Article abstract of DOI:10.1016/S0040-4020(96)01051-4

A new procedure for the synthesis of 2-azabicyclo[3.3.1]nonanes by intramolecular carboradical cyclization of 4-(trichloroacetamido)cyclohexenes substituted with an electron withdrawing substituent tester or nitrile) is described. The procedure allows the preparation of synthetically interesting azabicyclos 14 and 15 in nearly 70% yield.

Full text of DOI:10.1016/S0040-4020(96)01051-4

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