Pentacoordinate acyclic and cyclic anionic oxysilicates. A 29Si NMR and x-ray structural study

DOI: 10.1021/ja00162a039

Source and publish data:

Journal of the American Chemical Society p. 2341 - 2348 (1990)

Update date:2022-08-03

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Authors:

Swamy, K.C. Kumara

Chandrasekhar

Harland, John J.

Holmes, Joan M.

Day, Roberta O.

Holmes, Robert R.

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Article abstract of DOI:10.1021/ja00162a039

Variable temperature ²⁹Si NMR spectral measurements revealed the formation of acyclic anionic silicates, [R_n′Si(OR)_5-n][K,18-crown-6], n = 0-3, from reactions of alkoxy and aryloxysilanes with the respective potassium alko

Full text of DOI:10.1021/ja00162a039

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