Bulletin of the Chemical Society of Japan p. 707 - 711 (1997)
Update date:2022-07-31
Topics:
Murase, Noriaki
Maruoka, Keiji
Ooi, Takashi
Yamamoto, Hisashi
A new, general synthetic method of six-membered carbocycles has been demonstrated, which involves the stereo-controlled cyclization of olefinic epoxides with methylaluminum bis(4-bromo-2,6-di-t-butylphenoxide) (MABR) via the epoxide rearrangement and subsequent intramolecular ene reaction with high stereoselectivity. This strategy is shown to be highly useful in the stereoselective synthesis of the basic skeleton of various terpenes.
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Doi:10.1016/S0040-4039(97)00457-7
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(1999)Doi:10.1007/BF02742842
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(2007)Doi:10.1016/S0022-328X(00)95097-6
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