Tetrahedron Letters p. 5331 - 5334 (1998)
Update date:2022-08-03
Topics:
Xiao, Dengming
Zhang, Zhaoguo
Jiang, Qiongzhong
Zhang, Xumu
New C2-symmetric chiral amines with a rigid bicyclic framework have been synthesized via hydrogenation of monoazides catalyzed by 5% Pd/C in methanol. Enantiomerically pure 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes were made from readily available materials.
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