Synthesis p. 230 - 236 (1996)
Update date:2022-09-26
Topics:
Albrecht, Markus
The synthesis of the oligo(catechol) systems 1-4 with different substituents, length of the connecting spacer, and number of catechol units is achieved by the use of various coupling reactions (e.g. Wurtz, Glaser-Eglinton, Stephens-Castro). In order to do this methods of preparing the building blocks, 2,3-dimethoxybenzyl bromides 5, 2,3-dimethoxyphenylacetylene (17), or 1,4-dibromo-2,3-dimethoxybenzene (23) have been developed starting with simple catechol (benzene-1,2-diol) derivatives.
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Doi:10.1016/S0040-4020(97)00415-8
(1997)Doi:10.1021/ja971007s
(1997)Doi:10.1016/S0040-4039(97)00865-4
(1997)Doi:10.1002/ejoc.201402065
(2014)Doi:10.1021/jo900414n
(2009)Doi:10.1016/S0022-328X(96)06952-5
(1997)
