Direct Proton-Transfer Reaction via a Transient Hydrogen Bond Bridged Allyl Anion System on the Models of Cycloheptatrienes and Propene

Article abstract of DOI:10.1021/jo00389a007

The base-catalyzed intramolecular proton transfer in cycloheptatriene derivatives and propene has been investigated both theoretically and experimentally.A direct 1,3-intramolecular proton shift was observed in cycloheptatriene derivatives, the shift proc