Oxidation of allylselenides with the sharpless AD-reagents

DOI: 10.1016/S0040-4039(97)00596-0

Source and publish data:

Tetrahedron Letters p. 3315 - 3318 (1997)

Update date:2022-07-30

Topics:

Authors:

Krief, Alain

Colaux, Catherine

Dumont, Willy

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Article abstract of DOI:10.1016/S0040-4039(97)00596-0

Allylselenides are efficiently oxidized by AD-mix reagents. Oxidation takes chemoselectively place on the selenium atom of allylselenides bearing a methylseleno or a phenylseleno moiety, but chemoselectively occurs on the C,C double bond of the corresponding o-nitrophenyl derivatives.

Full text of DOI:10.1016/S0040-4039(97)00596-0

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