Tetrahedron p. 6171 - 6182 (1997)
Update date:2022-08-05
Topics:
Craig, Donald C.
Edwards, Gavin L.
Muldoon, Craig A.
Treatment of the para -toluenesulfonyl iodide adducts of a series of I-substituted 5-hexenols with K[N(TMS)2]] gave 2,6-disubstituted tetrahydropyrans with excellent cis-diastereoselectivity. The corresponding pentenols gave the 2,5-disubstituted tetrahydrofurans as 1:1 cis:trans mixtures.
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(1997)
