Reduction of dicarbapentaboranes(5) to 1,2-diborata-4-boracyclopendienes: Antiaromatic compouds with 4π-electron systems

DOI: 10.1002/anie.199708531

Source and publish data:

Angewandte Chemie - International Edition in English p. 853 - 855 (1997)

Update date:2022-08-04

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Authors:

Unverzagt

Winkler Winkler

Brock Brock

Hofman Hofman

Von Rague Schleyer

Massa Massa

Berndt Berndt

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Article abstract of DOI:10.1002/anie.199708531

Instead of tetragonal pyramids like 1, the antiaromatic 1,2-diborata-4-boracyclopentadiene five-membered rings 3 are formed on two-electron reduction of dicarbapentaboranes(5) 2.

Full text of DOI:10.1002/anie.199708531

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