Ruthenium-mediated dehydration of benzaldehyde oxime. X-ray crystal structure of the mixed-valence compound [RuBr(N≡CPh)5][RuBr4(N≡CPh)2] · PhCH2OH

DOI: 10.1016/S0277-5387(96)00574-8

Source and publish data:

Polyhedron p. 2429 - 2433 (1997)

Update date:2022-08-03

Topics:

Authors:

Kukushkin, Yuri N.

Bavina, Marina V.

Zinchenko, Andrey V.

Belsky, Vitaly K.

Kukushkin, Vadim Yu.

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Article abstract of DOI:10.1016/S0277-5387(96)00574-8

The reaction between RuBr₃ · xH₂O and benzaldehyde oxime in aqueous 6 M HBr results in facile metal-assisted dehydration of the oxime and concomitant partial reduction of ruthenium(III) to produce the mixed-valence ruthenium(III)-ruthenium(II) compound [RuBr(N≡CPh)₅][RuBr₄(N≡CPh)₂]. This ionic complex has been structurally characterized as the monobenzyl alcohol solvate, [RuBr(N≡CPh)₅][RuBr₄(N≡CPh)₂] · PhCH₂OH.

Full text of DOI:10.1016/S0277-5387(96)00574-8

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Product name:RuBr(NCC₆H₅)5⁽¹⁺⁾*RuBr₄(NCC₆H₅)2^(1-)*C₆H₅CH₂OH=[RuBr(NCC₆H₅)5][RuBr₄(NCC₆H₅)2]*C₆H₅CH₂OH

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