Tetrahedron Letters p. 3471 - 3474 (1997)
Update date:2022-08-03
Topics:
Clayden, Jonathan
Nelson, Adam
Warren, Stuart
Dehydration of diphenylphosphinoyl diols (synthesised by asymmetric dihydroxylation of allylic phosphine oxides) gives γ-hydroxy vinyl phosphine oxides. Some diastereoselective reactions of vinyl phosphine oxides with hydrogen, carbon and heteroatomic nucleophiles are discussed.
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