Journal of Fluorine Chemistry p. 187 - 191 (1997)
Update date:2022-07-29
Topics:
Van Der Puy, Michael
The preparation, isomerization, and utility of CF3CCl=CHCH2Cl as a 4-carbon reagent for the incorporation of a trifluoromethyl group is described. The regiochemistry observed for charged intermediates derived from CF3CCl=CHCH2Cl was consistent with MNDO calculated partial charges at C-1 and C-3. The anion-stabilizing and cation-destabilizing effects of the trifluoromethyl group were dominant.
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(1997)Doi:10.1021/ja513027s
(2015)Doi:10.1039/DT9770002038
()Doi:10.1246/bcsj.72.865
(1999)Doi:10.1016/S0960-894X(97)00318-1
(1997)Doi:10.1016/S0008-6215(97)00143-2
(1997)
