A new series of biologically potent cis-dioxomolybdenum(VI) complexes of fluoroimines

Article abstract of DOI:10.1080/00945719708000225

The modern physico-chemical, spectroscopic and biochemical methods have proved an important tool to elucidate the constitution of reactive transition metal compounds. This article presents a brief account of the synthesis and stereochemistry of dioxomolybdenum(VI) complexes of fluoroimines. The mononuclear complexes were obtained by bimolar reactions of dioxobis(2,4-pentanedionato-O,O′)molybdenum(VI) with the monobasic bidentate fluoroimines containing N^∩S and N^∩O as the binding sites. Based on chemical analyses, IR and NMR spectra, conductance measurements and molecular weight determinations an octahedral geometry has been assigned to the newly synthesized products. The possibility of potential uses of these complexes as fungicides and bactericides, studied in vitro are also discussed.

Full text of DOI:10.1080/00945719708000225

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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A New Series of
Biologically Potent cis-
Dioxomolybdenum(VI)
Complexes of Fluoroimines
R. V. Singh a , S. C. S. Jadon a & Neeti Gupta a
a Department of Chemistry , University of
Rajasthan , Jaipur, 302 004, India
Published online: 20 Aug 2006.
To cite this article: R. V. Singh , S. C. S. Jadon & Neeti Gupta (1997) A New Series of
Biologically Potent cis-Dioxomolybdenum(VI) Complexes of Fluoroimines, Synthesis
and Reactivity in Inorganic and Metal-Organic Chemistry, 27:5, 759-773, DOI:
10.1080/00945719708000225
To link to this article: http://dx.doi.org/10.1080/00945719708000225
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