Radical-induced S(N)1 substitution reactions

DOI: 10.1016/0040-4039(96)00782-4

Source and publish data:

Tetrahedron Letters p. 4365 - 4368 (1996)

Update date:2022-08-04

Topics:

Authors:

Peukert Peukert

Giese Giese

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Article abstract of DOI:10.1016/0040-4039(96)00782-4

Solvolysis of radicals 17 and 18 yielded the same products 19-23. This indicates that the radical-induced substitution of the phosphate group occurs via radical cation 24 as common intermediate.

Full text of DOI:10.1016/0040-4039(96)00782-4

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