Journal of Organometallic Chemistry p. 9 - 12 (1997)
Update date:2022-08-04
Topics:
Diederichsen, Ulf
Curran, Dennis P.
Reactions of alkyl halides (R1X) with acyltriphenylgermanes (R2COGePh3) under radical conditions provide mixtures of ketones (R1COR2), diketones (R2COCOR2), alkanes (R1H) and alkenes. These products arise from radical-radical reactions, and the results suggest that bimolecular addition reactions of alkyl radicals to acylgermanes are too slow to propagate radical chains.
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