Bimolecular reactions of alkyl halides and acylgermanes: Formation of ketones, diketones, and other products by radical-radical reaction

DOI: 10.1016/S0022-328X(96)06677-6

Source and publish data:

Journal of Organometallic Chemistry p. 9 - 12 (1997)

Update date:2022-08-04

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Authors:

Diederichsen, Ulf

Curran, Dennis P.

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Article abstract of DOI:10.1016/S0022-328X(96)06677-6

Reactions of alkyl halides (R¹X) with acyltriphenylgermanes (R²COGePh₃) under radical conditions provide mixtures of ketones (R¹COR²), diketones (R²COCOR²), alkanes (R¹H) and alkenes. These products arise from radical-radical reactions, and the results suggest that bimolecular addition reactions of alkyl radicals to acylgermanes are too slow to propagate radical chains.

Full text of DOI:10.1016/S0022-328X(96)06677-6

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