Angewandte Chemie - International Edition p. 8678 - 8681 (2008)
Update date:2022-08-04
Topics:
Kim, Hyunwoo
Nguyen, Yen
Lough, Alan J.
Chin, Jik
(Chemical Equation Presented) Bucklingunder the strain: Steric strain was used to drive the diaza-Cope rearrangement to completion (see scheme) with a high degree of stereospecificity (>99.5% ee), as evidenced by chiral-phase HPLC and crystal data. There is good agreement between the experimental and computational values for the rate and equilibrium constants for the rearrangement.
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