Stereoselective synthesis of neo-C-glycopeptide building blocks: Towards a flexible and control-oriented design as probes for carbohydrate-protein interactions

DOI: 10.1016/S0960-894X(97)00255-2

Source and publish data:

Bioorganic and Medicinal Chemistry Letters p. 1537 - 1542 (1997)

Update date:2022-07-30

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Authors:

Arya, Prabhat

Dion, Sylvain

Shimizu, George K. H.

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Article abstract of DOI:10.1016/S0960-894X(97)00255-2

Neo-C-glycopeptides (1-4) have been synthesized as building blocks to obtain higher neo-C-glycopeptides as probes for studying carbohydrate-protein interactions. A convergent approach for the synthesis of 4 has been developed, in which two galactose units are attached to a glycine derivative in a stepwise procedure (reductive amination followed by amide coupling) and finally coupling to the protected dipeptide having a free amino group on the side chain.

Full text of DOI:10.1016/S0960-894X(97)00255-2

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