Total synthesis of phenazinomycin and its enantiomer via high-pressure reaction

DOI: 10.1016/S0040-4039(97)01068-X

Source and publish data:

Tetrahedron Letters p. 4993 - 4996 (1997)

Update date:2022-08-03

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Authors:

Kinoshita, Yoshiharu

Kitahara, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(97)01068-X

Total synthesis of phenazinomycin a rare type of phenazine antibiotic, was achieved by using high pressure reaction. Chiral sesquiterpene moiety in the side chain was synthesized employing (S)-3-hydroxy-2,2- dimethylcyclohexanone as a chiral source.

Full text of DOI:10.1016/S0040-4039(97)01068-X

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Product name:(Z)-5-((S)-2,2-Dimethyl-6-methylene-cyclohexyl)-3-phenylsulfanyl-pent-2-enoic acid methyl ester

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