Substitution Reaction of Organic Halide by Trimethylsilyl Isothiocyanate: Formation of Thiocyanate and Its Rearrangement to Isothiocyanate

DOI: 10.1246/bcsj.60.2692

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2692 - 2694 (1987)

Update date:2022-08-03

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Authors:

Nishiyama, Kozaburo

Oba, Makoto

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Article abstract of DOI:10.1246/bcsj.60.2692

The reaction of organic halide with trimethylsilyl isothiocyanate (TMSTC) gave thiocyanate 1 and its isomerized isothiocyanate 2.Details of the substitution and the isomerization reactions were examined.

Full text of DOI:10.1246/bcsj.60.2692

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