Use of Winterfeldt's template to control the C-2' configuration in the synthesis of strigol-type compounds

DOI: 10.1016/S0040-4020(98)00077-5

Source and publish data:

Tetrahedron p. 3439 - 3456 (1998)

Update date:2022-08-03

Topics:

Authors:

Roehrig, Susanne

Hennig, Lothar

Findeisen, Matthias

Welzel, Peter

Mueller, Dietrich

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Article abstract of DOI:10.1016/S0040-4020(98)00077-5

A route comprising (i) a cycloaddition reaction of citraconic anhydride with the Winterfeldt auxiliary, (ii) hydride reduction of the cycloadduct, (iii) a (formal) ether formation, and (iv) a cycloreversion reaction allows efficient stereocontrol at C-2' in the synthesis of strigol and its structural analogues.

Full text of DOI:10.1016/S0040-4020(98)00077-5

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