Use of Winterfeldt's template to control the C-2' configuration in the synthesis of strigol-type compounds

DOI: 10.1016/S0040-4020(98)00077-5

Source and publish data:

Tetrahedron p. 3439 - 3456 (1998)

Update date:2022-08-03

Topics:

Authors:

Roehrig, Susanne

Hennig, Lothar

Findeisen, Matthias

Welzel, Peter

Mueller, Dietrich

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(98)00077-5

A route comprising (i) a cycloaddition reaction of citraconic anhydride with the Winterfeldt auxiliary, (ii) hydride reduction of the cycloadduct, (iii) a (formal) ether formation, and (iv) a cycloreversion reaction allows efficient stereocontrol at C-2' in the synthesis of strigol and its structural analogues.

Full text of DOI:10.1016/S0040-4020(98)00077-5

Products guided by the article

Product name:2H-Cyclopenta[b]furan-2-one, 3,3a,4,6a-tetrahydro-3-(hydroxymethylene)-, [3aS-(3Z,3aalpha,6aalpha)]- (9CI)

Cas No:194468-85-4

R&D Labs maybe for 194468-85-4

Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang

Relevant to this article

Chain Entropy Beats Hydrogen Bonds to Unfold and Thread Dialcohol Phosphates inside Cyanostar Macrocycles to Form [3]Pseudorotaxanes

Doi:10.1021/acs.joc.0c02887
(2021)
Copper-Catalyzed Direct sp²C-H Silylation of Arylamides Using Disilanes

Doi:10.1021/acs.orglett.1c01129
(2021)
Synthesis and evaluation of new Hsp90 inhibitors based on a 1,4,5-trisubstituted 1,2,3-triazole scaffold

Doi:10.1021/jm401536b
(2014)
Cp?Co(III)-Catalyzed C-H Acylmethylation of Arenes by Employing Sulfoxonium Ylides as Carbene Precursors

Doi:10.1021/acs.orglett.8b02796
(2018)
Chemical Upcycling of Waste Poly(bisphenol A carbonate) to 1,4,2-Dioxazol-5-ones and One-Pot C?H Amidation

Doi:10.1002/cssc.202100885
(2021)
C-H activation by [bis(dialkoxyphosphino)ethane]platinum(0) and [bis(diaminophosphino)ethane]platinum(0) complexes: Platinum-platinum dimer formation limits yields

Doi:10.1021/om00020a012
(1994)

Article Doi