An external chiral ligand controlled enantioselective opening of oxirane and oxetane by organolithiums

DOI: 10.1016/S0040-4020(97)00701-1

Source and publish data:

Tetrahedron p. 10699 - 10708 (1997)

Update date:2022-08-03

Topics:

Authors:

Mizuno, Masashi

Kanai, Motomu

Iida, Akira

Tomioka, Kiyoshi

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Article abstract of DOI:10.1016/S0040-4020(97)00701-1

Enantioselective nucleophilic opening reactions of cyclohexene oxide and 3-phenyloxetane were achieved by the combination of an external chiral ligand and organolithiums in the presence of boran trifluoride to give the corresponding alcohols in up to 47% ee.

Full text of DOI:10.1016/S0040-4020(97)00701-1

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