Synthesis of liverwort sesquiterpene (-)-isocuparene (herbertene) via a Diels-Alder reaction using phenylethylamine as chiral auxiliary

DOI: 10.1016/S0957-4166(97)00313-3

Source and publish data:

Tetrahedron Asymmetry p. 2731 - 2738 (1997)

Update date:2022-08-05

Topics:

Authors:

Tori, Motoo

Miyake, Takahiro

Hamaguchi, Tomonobu

Sono, Masakazu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(97)00313-3

The imine of 2-methylcyclopentanone with (S)-(-)-phenylethylamine was subjected to reaction with methyl propiolate and the product was transformed into (-)-isocuparene by use of a Diels-Alder reaction to construct the aromatic ring.

Full text of DOI:10.1016/S0957-4166(97)00313-3

Products guided by the article

Product name:[2-Methyl-cyclopent-(Z)-ylidene]-((S)-1-phenyl-ethyl)-amine

Cas No:195251-72-0

R&D Labs maybe for 195251-72-0

HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Engineering Research Center of Pesticide, Heilongjiang Province

Contact:+86-451-86609001

Address:No.74 of Xuefu Road, Nangang District,
NINGBO PANGS CHEM INT’L CO., LTD.

Contact:+86-0574-27666801

Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Beijing eternalchem Co,. Ltd

Contact:+86-10-59484199

Address:No.58-A1026 Liangguan Street

Relevant to this article

Doi:10.1016/S0022-328X(00)95165-9
(1974)
Structure-activity studies for a novel series of tricyclic substituted hexahydrobenz[e]isoindole α(1A) adrenoceptor antagonists as potential agents for the symptomatic treatment of benign prostatic hyperplasia (BPH)

Doi:10.1021/jm990567u
(2000)
Synthesis and study of antiinflammatory and analgesic activity of 2-arylaminocinchoninic acid hydrazides and β-(1-carboxyethylidene)hydrazides

Doi:10.1007/BF02464122
(1997)
Rhodium(I)-Catalyzed successive double cleavage of Carbon-Carbon bonds of strained spiro cyclobutanones

Doi:10.1021/ja971949x
(1997)
Syntheses and evaluation of naphthalenyl- and chromenyl-pyrrol-benzoic acids as potent and selective retinoic acid receptor α agonists

Doi:10.1016/S0960-894X(00)00067-6
(2000)
An economical synthesis of Lewis X, sialyl lewis X and their α-galactosyl analogues

Doi:10.1080/07328309708005732
(1997)

Article Doi