Stereospecific Allylation of a Serine-derived Zinc/Copper Reagent. Synthesis of Substituted Pipecolic Acid Derivatives

DOI: 10.1055/s-1997-5769

Source and publish data:

Synlett p. 789 - 790 (1997)

Update date:2022-08-05

Topics:

Authors:

Jackson, Richard F.W.

Turner, Debra

Block, Michael H.

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Article abstract of DOI:10.1055/s-1997-5769

Serine-derived zinc/copper reagents 1 and 2 add to enantiomerically pure (η³-allyl)iron tetracarbonyl salts in fair to good yield in a stereospecific fashion. The vinylsulfones 10-12 can be converted into 4-methylpipecolic acid derivatives 19-21 in a two-step process comprising epoxidation and Zn/TMSCl mediated cyclisation.

Full text of DOI:10.1055/s-1997-5769

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