Preparation and synthetic applications of lithiated vinyl sulfones derived from 3-buten-1-ol and 4-penten-1-ol

DOI: 10.1016/S0040-4020(97)00725-4

Source and publish data:

Tetrahedron p. 11449 - 11464 (1997)

Update date:2022-08-03

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Authors:

Caturla, Francisco

Najera, Carmen

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Article abstract of DOI:10.1016/S0040-4020(97)00725-4

Vinyl sulfones (E)-4-tosyl-3-bulen-1-ol (2) and its MOM-derivative 6, prepared by iodosulfonylation-dehydroiodination of 3-buten-1-ol(1), are regio and stereoselectively lithiated at die 4-position to afford intermediates 3 and 7, respectively. Tile prote

Full text of DOI:10.1016/S0040-4020(97)00725-4

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